开孔型橡塑多孔材料的应力-应变行为

研究了拉伸应力对开孔型橡胶一塑料多孔材料形态结构和力学性能的影响。结果表明：拉伸应力的增加使橡塑多孔材料产生了形变，导致了气泡孔孔径、透水率的增大。不同定伸长率试样的回缩率是有差异的，定伸长愈大，试样的回缩形变就愈大；回缩形变随时间的变化主要发生在拉伸试样恢复期的初期，30d后试样的形变基本稳定。     

固态水玻璃粉末合成硅基介孔材料的研究

以固态水玻璃粉末为硅源,三甲基十六烷基溴化铵(CTAB)为模板剂,成功合成了硅基介孔材料。利用 XRD,SEM和TEM技术对介孔材料的结构进行表征,研究了介孔材料在合成过程中CTAB与Si的摩尔比、体系pH值、反应温度及烧成制度对其结构的影响。结果表明:在CTAB与Si的摩尔比为0．15,体系pH值为8．5,反应温度为70 ℃,煅烧升温速度为5℃／min时,合成的样品微观结构较好,孔道分布均匀,且长程有序化程度高。     

OPC技术在WINCC与组态王通讯中的应用

本文是利用OPC（OLE for Process Control）技术,通过公司现有的以太网,实现了组态王数据与远程WINCC的通讯,解决了不同组态软件之间的远程通讯难题.     

一种正方化有序树图布局算法

针对现有正方化树图有序性差、有序树图正方化性能差的问题,提出一种正方化有序树图布局算法——SOTLA,首先将多个节点捆绑组合构造大权值节点;然后按平均长宽比最接近1和沿最短边方向填充路径限制的原则对节点进行布局;通过对每一组合节点分治并重复上述过程进行布局,最终完成所有单个节点的布局.将该算法应用于50组具有层次结构和数据值大小悬殊特点的农药残留量检测数据中,得到了较好的可视化效果.将该算法与现有的Squarified,Pivot,Strip和Spiral 4种布局算法就平均长宽比、连续性、可读性、稳定性和稳定的平衡性5项评价指标进行对比,实验结果表明,文中算法在连续性和平均长宽比性能上具有明显优势,其可读性、稳定性和稳定的平衡性指标也表现良好.     

Morphology of epoxy resin modified with silyl‐crosslinked urethane elastomer

Silyl‐crosslinked urethane elastomer modifying epoxy resin has drawn much interest. Here the triethoxysilyl‐terminated polycaprolactone elastomer (PCL‐TESi) modifying diglycidylether of bisphenol A epoxy resins (DGEBA) system was chosen, and then the effect of the type of curing agent on the phase structure of the studied epoxy resin system was investigated. The modified systems were obtained with different phase structures by varying the formulations of the curing agent. It was experimentally shown that with the addition of aminosilane (KBE‐9103), the crosslinked density was greatly increased. The cured system also showed from SEM and TEM analysis that addition of KBE‐9103 increased the compatibility between the PCL‐TESi and DGEBA, which made the ductility of the system decrease, but also indicated from TEM that addition of much KBE‐9103 made the reacted silicone particles coagulate each other. The state of phase separation from TEM in the cured system was theoretically explained. These would serve the deeper studies of the mechanism of silyl‐crosslinked urethane elastomer modifying epoxy resin in the future. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 97: 611–619, 2005     

机动车制动液的研制

介绍了合成型机动车制动液的生产和配方，讨论了物料组成对产品的影响。     

缠绕用无溶剂低温固化双马来酰亚胺树脂体系

在乙烯基苄基化合物改性双马来酰亚胺树脂体系中添加烯丙基苯酚活性稀释剂,得到了粘度小于1000 mPa·s,加工适用期大于8 h,在150～155℃完成固化与后固化、适用于缠绕成型工艺的树脂体系。增韧改性后,该树脂的玻璃化转变温度达到261℃,拉伸强度和弯曲强度分别为73 MPa和133 MPa。     

Isotopic Oxygen Exchange and EPR Studies of Superoxide Species on the SrF2/La2O3 Catalyst

By using the in situ IR spectroscopy, the superoxide species (O₂⁻), characterized by the O–O stretching peak at 1130 cm⁻¹, was detected on the SrF₂/La₂O₃ catalyst at temperatures up to 973 K. The introduction of ¹⁸O₂ isotope caused the 1130 cm⁻¹ peak to shift to lower wavenumbers (1095 and 1064 cm⁻¹), consistent with the assignment of the spectra to the superoxide species. A good correlation between the rate of the disappearance of the O₂⁻ species and that of the formation of C₂H₄ was observed, suggesting that O₂⁻ was the active oxygen species responsible for the oxidative coupling of methane (OCM) on the SrF₂/La₂O₃ catalyst. This conclusion was reinforced by the EPR experiments (g_xx = 2.0001, g_yy = 2.0045, g_zz = 2.0685), showing that O₂⁻ was the only paramagnetic oxygen species detectable on the O₂-preadsorbed SrF₂/La₂O₃ catalyst. These results suggest that superoxide O₂⁻ can be a stable active oxygen species, whose role in the OCM reaction cannot be overlooked.     

Modeling the curing kinetics for a modified bismaleimide resin using isothermal DSC

The kinetics of curing for a modified bismaleimide (BMI) resin was investigated to ascertain a suitable cure model for the material. The resin system used in this study was composed of 4,4′‐bismaleimidodiphenylmethane (BMIM) and 0,0′‐diallyl bisphenol A (DABPA, DABA). The BMIM was the base monomer and the DABPA was the modified agent. A series of isothermal DSC runs provided information about the kinetics of cure in the temperature range 170–220°C. Regardless of the different temperatures, the shape of the conversion curves was similar, and this modified BMI resin system underwent an nth‐order cure reaction. Kinetic parameters of this BMI resin system, including the reaction model, activation energy, and frequency factor, were calculated. From the experimental data, it was found that the cure kinetics of this resin system can be characterized by a first‐order kinetic model. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 3338–3342, 2004     

由3-吲哚乙酰胺制备色胺

色胺(Tryptamine)，化学名为3-(2-氨乙基)吲哚，是合成具有治疗脑动脉硬化作用的长春胺和脱水长春胺乙酯等生物碱的中间体。文献报道的合成方法较多，如以γ-氯丁醛和苯肼缩合法、3-氯丙基丙二酸乙酯和氯化重氮苯偶合法、乙酰吲哚满基酮为原料的Wittuig反应法、以丙烯腈和丙二酸乙酯为原料的6步法等，这些方法或总收率低、或中间体制备困难、或反应条件苛刻、